21% Efficiency Silicon Heterojunction Solar Cells Produced with Very High Frequency Pecvd

نویسندگان

  • A. Descoeudres
  • L. Barraud
  • P. Bôle Rothen
  • S. De Wolf
  • B. Demaurex
  • J. Geissbühler
  • Z. C. Holman
  • C. Ballif
چکیده

Silicon heterojunction solar cells have high opencircuit voltages thanks to excellent passivation of the wafer surfaces by thin intrinsic amorphous silicon (aSi:H) layers deposited by plasma-enhanced chemical vapor deposition (PECVD). By using in-situ plasma diagnostics and ex-situ film characterization, we show that the best a-Si:H films for passivation are produced from deposition regimes close to the amorphous-tocrystalline transition. Based upon this finding, layers deposited in a large-area very high frequency (40.68 MHz) PECVD reactor were optimized for heterojunction solar cells. 4 cm solar cells were produced with fully industry-compatible processes, yielding open-circuit voltages up to 725 mV and aperture area efficiencies up to 21%.

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تاریخ انتشار 2011